By Lawrence J. Dunne, George Manos
Channels of nanotubular dimensions exist in various fabrics (examples are carbon nanotubes and the nanotubular channels of zeolites and zeotypes) and express promise for varied purposes as a result of their specific houses. considered one of their most vital houses is their means to adsorb molecules and those might exist in numerous levels.
"Adsorption and part Behaviour in Nanochannels and Nanotubes" presents a great assessment of modern and present paintings on adsorption on nanometerials. it truly is a magnificent choice of papers facing the adsorption and part behaviour in nanoporous fabrics from either experimental and theoretical perspectives.
"Adsorption and section Behaviour in Nanochannels and Nanotubes" specializes in carbon nanotubes in addition to zeolites and similar materials.
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Additional info for Adsorption and Phase Behaviour in Nanochannels and Nanotubes
Sebastian J, Pillai RS, Peter SA, Jasra RV (2007) Sorption of N2 , O2 , and Ar in Mn(II)Exchanged Zeolites A and X Using Volumetric Measurements and Grand Canonical Monte Carlo Simulation. Ind. Eng. Chem. Res. 46:6293–6302 130. Sarkisov L, Düren T, Snurr RG, (2004) Molecular Modelling of Adsorption in Novel Nanoporous Metal-Organic Materials. Mol. Phys. 102:211–221 131. Düren T, Snurr RQ (2004) Assessment of Isoreticular Metal-Organic Frameworks for Adsorption Separations: A Molecular Simulation Study of Methane/n-Butane Mixtures.
Chem. Eng. Commun. 174:201–214 144. Talu O, Zwiebel I (1986) Multicomponent Adsorption Equilibria of Nonideal Mixtures. AIChE J 32:1263–1276 145. Denayer JFM, De Meyer K, Martens JA, Baron G (2003) Molecular Competition Effects in Liquid Phase Adsorption of Long-Chain n-Alkane Mixtures in ZSM-5 Zeolite Pores. Angew. Chem. Int. Ed. 42:2774–2777 146. Chempath S, Denayer JFM, De Meyer KMA, Baron G, Snurr RQ (2003) Adsorption of Liquid Phase Alkane Mixtures in Silicalite: Simulations and Experiment.
For n-pentane, the γ-cages are the preferred adsorption sites in H-ZK-5, whereas in K-ZK-5 the α-cages are the preferred adsorption sites. This difference is caused by the presence of the potassium cations in the γ-cages of K-ZK-5 which constraints the adsorption in these cages. Lachet et al.  investigated the adsorption and coadsorption of m-xylene and p-xylene in the faujasites NaY and KY. Results of the single component and binary mixture studies showed, in agreement with the experiments, that the exchange of Na+ ions by K+ ions had almost no effect on the amount of adsorbed p-xylene but leads to a significant decrease of the m-xylene adsorption capacity and a reversal of the adsorption selectivity.
Adsorption and Phase Behaviour in Nanochannels and Nanotubes by Lawrence J. Dunne, George Manos